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Bioinspired Deformable Antireflective Materials by Block Copolymer Self-Assembly
  • You, Dong Won ;
  • Yoon, Jeongbin ;
  • Kim, Seonghyun ;
  • Yang, Geon Gug ;
  • Lee, Chan Woo ;
  • Shin, Jonghwa ;
  • Hong, Seungbum ;
  • Kim, Jang Hwan ;
  • Kim, Sang Ouk
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Publication Year
2025-04-23
Journal
ACS Applied Materials and Interfaces
Publisher
American Chemical Society
Citation
ACS Applied Materials and Interfaces, Vol.17 No.16, pp.24610-24619
Keyword
antireflectionbioinspiredblock copolymernanopatterningself-assembly
Mesh Keyword
AntireflectionAntireflectiveAntireflective surfacesBioinspiredBlock co polymersBlock copolymer self-assemblyDevice geometriesNanoPatterningOptical-Performance
All Science Classification Codes (ASJC)
Materials Science (all)
Abstract
Antireflective surface is a crucial component for high-performance photonic systems but has been principally focused on hard, flat device geometry. We present an antireflective strategy for deformable device geometry that combines superior optical performance with mechanical robustness. Bioinspired nanohole arrays are embedded into a transparent polymer layer by exploiting block copolymer self-assembly. The resultant nanoengineered surface reduces light reflection by over 70% across the visible spectrum compared to a nonpatterned surface, owing to gradual refractive index along nanohole geometry that mediates optical impedance mismatch with the air interface, as supported by simulation studies. Adoption of interconnected nanostructures facilitates efficient dissipation of external mechanical stress, ensuring high mechanical resilience, even under repeated nonlinear deformation cycles. Furthermore, multifunctionality with self-cleaning capabilities is demonstrated, attributed to genuine hydrophobicity of nanostructured geometry. Our straightforward strategy delivers a promising solution for next-generation optical and optoelectronic systems commonly involved in complex and deformable design configurations.
ISSN
1944-8252
Language
eng
URI
https://aurora.ajou.ac.kr/handle/2018.oak/38276
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105003604827&origin=inward
DOI
https://doi.org/10.1021/acsami.5c02740
Journal URL
http://pubs.acs.org/journal/aamick
Type
Article
Funding
This work was supported by the National Creative Research Initiative (CRI) Center for Multi-Dimensional Directed Nanoscale Assembly (2025R1A3A2033061) and the National Research Foundation of Korea (NRF), funded by the Ministry of Science. This work was also supported by the LG Display Co. (G01240329).
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Kim, Jang Hwan 김장환
Department of Materials Science Engineering
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