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Stereoselective Total Synthesis of (–)-Hedycoropyran A
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Advisor
이동주
Affiliation
아주대학교 일반대학원
Department
일반대학원 약학과
Publication Year
2022-02
Publisher
The Graduate School, Ajou University
Keyword
(–)-Hedycoropyran ADehydrogenative CycloetherificationDiastereoselectivityNatural Producttrans-2-Alkyl-6-aryl-36-dihydro-2H-pyran
Description
학위논문(석사)--아주대학교 일반대학원 :약학과,2022. 2
Alternative Abstract
The second stereoselective total synthesis of (–)-hedycoropyran A (1) has been accomplished in 10 steps with 4.73% overall yield from the readily available alkene 6. The key features of our strategy include (1) highly diasteoreoselective construction of trans-2-alkyl-6-aryl-3,6-dihydro-2H-pyran framework and (2) substrate-controlled trans-dihydroxylation at C(3)/C(4)
Language
eng
URI
https://aurora.ajou.ac.kr/handle/2018.oak/21315
Journal URL
https://dcoll.ajou.ac.kr/dcollection/common/orgView/000000031764
Type
Thesis
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