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Stereoselective Total Synthesis of (–)-Hedycoropyran A
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dc.contributor.advisor이동주-
dc.contributor.author안병연-
dc.date.issued2022-02-
dc.identifier.other31764-
dc.identifier.urihttps://aurora.ajou.ac.kr/handle/2018.oak/21315-
dc.description학위논문(석사)--아주대학교 일반대학원 :약학과,2022. 2-
dc.description.tableofcontentsI. Introduction 1 II. Results and Discussion 3 III. Conclusion 9 IV. Experimental Section 10 V. References 25-
dc.language.isoeng-
dc.publisherThe Graduate School, Ajou University-
dc.rights아주대학교 논문은 저작권에 의해 보호받습니다.-
dc.titleStereoselective Total Synthesis of (–)-Hedycoropyran A-
dc.typeThesis-
dc.contributor.affiliation아주대학교 일반대학원-
dc.contributor.department일반대학원 약학과-
dc.date.awarded2022. 2-
dc.description.degreeMaster-
dc.identifier.uciI804:41038-000000031764-
dc.identifier.urlhttps://dcoll.ajou.ac.kr/dcollection/common/orgView/000000031764-
dc.subject.keyword(–)-Hedycoropyran A-
dc.subject.keywordDehydrogenative Cycloetherification-
dc.subject.keywordDiastereoselectivity-
dc.subject.keywordNatural Product-
dc.subject.keywordtrans-2-Alkyl-6-aryl-3-
dc.subject.keyword6-dihydro-2H-pyran-
dc.description.alternativeAbstractThe second stereoselective total synthesis of (–)-hedycoropyran A (1) has been accomplished in 10 steps with 4.73% overall yield from the readily available alkene 6. The key features of our strategy include (1) highly diasteoreoselective construction of trans-2-alkyl-6-aryl-3,6-dihydro-2H-pyran framework and (2) substrate-controlled trans-dihydroxylation at C(3)/C(4)-
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