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Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction
  • 나현석 ;
  • 안선용 ;
  • 심재오 ;
  • 전경원 ;
  • 김학민 ;
  • 이열림 ;
  • 장원준 ;
  • 전병훈 ;
  • 노현석
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Publication Year
2019-07
Journal
Korean Journal of Chemical Engineering
Publisher
한국화학공학회
Citation
Korean Journal of Chemical Engineering, Vol.36 No.8, pp.1243-1248
Keyword
Water-gas ShiftCu-Zn-AlPrecipitation ProcesspHInjection Rate
Abstract
−To investigate the effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst, the pH value and injection rate in the precipitation process were systematically changed, and the water-gas shift reaction was carried out. The Cu-Zn-Al catalyst showed the highest CO conversion when the optimized synthesis parameters (i.e., pH=10-10.5 and injection rate=30ml/min) were employed. This is mainly due to the enhanced physicochemical properties such as a high Brunauer-Emmett-Teller surface area, small crystallite size, high Cu dispersion, and easier reducibility.
ISSN
0256-1115
Language
Eng
URI
https://aurora.ajou.ac.kr/handle/2018.oak/37378
https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART002488600
DOI
https://doi.org/10.1007/s11814-019-0309-8
Type
Article
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Jang, WonJun Image
Jang, WonJun장원준
Department of Environmental and Safety Engineering
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