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Effect of Pt catalyst on the condensable hydrocarbon content generated via food waste pyrolysis
  • Kim, Soosan ;
  • Lee, Chang Gu ;
  • Kim, Yong Tae ;
  • Kim, Ki Hyun ;
  • Lee, Jechan
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Publication Year
2020-06-01
Publisher
Elsevier Ltd
Citation
Chemosphere, Vol.248
Keyword
CatalystFood wastePyrolysisWaste disposalWaste management
Mesh Keyword
Benzene derivativesCarbon containingCarbon distributionEnvironmentally benignFree radical mechanismHydrocarbon contentInert atmospheresNon-condensable gasCatalysisFoodGasesHot TemperatureHydrocarbonsPlatinumPyrolysisRefuse Disposal
All Science Classification Codes (ASJC)
Environmental EngineeringEnvironmental ChemistryChemistry (all)PollutionPublic Health, Environmental and Occupational HealthHealth, Toxicology and Mutagenesis
Abstract
A Pt catalyst supported on activated carbon (Pt/AC) was used for an environmentally friendly thermal treatment of food waste under an inert atmosphere (i.e., pyrolysis). This catalyst influenced the amounts of condensable hydrocarbons and noncondensable gases but not that of the solid remaining after the pyrolysis; in particular, it contributed to shifting the carbon distribution from the condensable hydrocarbons to the noncondensable gases for the food waste pyrolysis. Moreover, its use suppressed the generation of harmful chemical compounds, especially at high temperatures. For example, a Pt/AC-catalyzed pyrolysis at 700 °C produced about 4 times fewer benzene derivatives than the same treatment without a catalyst; this probably occurred because the Pt sites catalyzed the decyclization reaction and/or the free radical mechanism, which is dominant in the thermal cracking of carbon-containing feedstock. This study suggests that a Pt/AC-catalyzed pyrolysis would be a more environmentally benign food waste treatment method.
Language
eng
URI
https://dspace.ajou.ac.kr/dev/handle/2018.oak/31121
DOI
https://doi.org/10.1016/j.chemosphere.2020.126043
Fulltext

Type
Article
Funding
This work was supported by a National Research Foundation of Korea (NRF) Grant funded by the Korean Government (Ministry of Education) (No. 2018R1D1A1A09082841 ).
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Lee, Chang-Gu  Image
Lee, Chang-Gu 이창구
Department of Environmental and Safety Engineering
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