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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | 박성준 | - |
| dc.contributor.author | 신동준 | - |
| dc.date.issued | 2024-02 | - |
| dc.identifier.other | 33714 | - |
| dc.identifier.uri | https://aurora.ajou.ac.kr/handle/2018.oak/39155 | - |
| dc.description | 학위논문(석사)--지능형반도체공학과,2024. 2 | - |
| dc.description.abstract | Organic electrochemical transistors (OECTs) have gained tremendous attention due to their low-voltage operation, high amplification, and ion-to-electron coupling. These advancements are particularly notable in the development of biocompatible and flexible sensors, as well as e-skin multifunctional circuits. Despite these advancements, the practical application of OECTs, where n-type and p-type materials complement each other, is challenging. This is largely due to the performance disparity between p-type and n-type organic mixed ionic-electronic conductors (OMIECs) used in OECT channels, with n-type OMIECs facing issues, such as low electron mobility, slow operation speed, and instability. To address these challenges, this study focuses on exploring the operational characteristics of n-type OECTs using newly synthesized X-material. The research demonstrates that OECTs utilizing X-material exhibit impressive performance metrics, including high charge carrier mobility, rapid transient response, and enhanced long-term stability. All results indicate that X-material can effectively complement p-type counterparts. Furthermore, the study introduces an innovative concept in the form of an anti-ambipolar electrochemical transistor. This transistor operates through ion injection-driven resistance modulation, presenting a novel approach to transistor design. Overall, this research significantly contributes to enhancing the performance of next-generation organic electronic devices, potentially revolutionizing the field. | - |
| dc.description.tableofcontents | 1. Background 1_x000D_ <br> 1.1 The emergence of organic electrochemical transistors 1_x000D_ <br> 1.2 OECTs working mechanisms 1_x000D_ <br> 1.3 Performance metrics of OECTs 1_x000D_ <br> 1.4 Heterojunction structure in organic transistors 2_x000D_ <br>2. Introduction 4_x000D_ <br> 2.1 Challenge of OECTs 4_x000D_ <br> 2.2 The rise of ladder type polymer 4_x000D_ <br> 2.3 X-material excellent candidate as n-type OMIEC 6_x000D_ <br>3. Results and discussion 7_x000D_ <br> 3.1 UV-Vis spectroelectrochemistry 7_x000D_ <br> 3.2 Ion mobility extraction 7_x000D_ <br> 3.3 Steady state response characteristics 8_x000D_ <br> 3.4 Electrochemical impedance spectroscopy 9_x000D_ <br> 3.5 Transient response and long-term stability 10_x000D_ <br> 3.6 Anti-ambipolar organic electrochemical transistors 11_x000D_ <br>4. Conclusion 13_x000D_ <br>5. Experimental section 14_x000D_ <br> 5.1 Materials 14_x000D_ <br> 5.2 Electrochemical measurements 14_x000D_ <br> 5.3 OECT fabrication 14_x000D_ <br> 5.4 Moving front experiment 15_x000D_ <br> 5.5 Characterization 15_x000D_ <br>6. References 33 | - |
| dc.language.iso | kor | - |
| dc.publisher | The Graduate School, Ajou University | - |
| dc.rights | 아주대학교 논문은 저작권에 의해 보호받습니다. | - |
| dc.title | 고성능 공핍모드 n형 유기전기화학트랜지스터 | - |
| dc.type | Thesis | - |
| dc.contributor.affiliation | 아주대학교 대학원 | - |
| dc.contributor.department | 일반대학원 지능형반도체공학과 | - |
| dc.date.awarded | 2024-02 | - |
| dc.description.degree | Master | - |
| dc.identifier.url | https://dcoll.ajou.ac.kr/dcollection/common/orgView/000000033714 | - |
| dc.subject.keyword | Heterojunction structure | - |
| dc.subject.keyword | Organic electrochemical transistors | - |
| dc.subject.keyword | Organic mixed ionic-electronic conductor | - |
| dc.subject.keyword | Side-chain free polymer | - |
| dc.description.alternativeAbstract | Organic electrochemical transistors (OECTs) have gained tremendous attention due to their low-voltage operation, high amplification, and ion-to-electron coupling. These advancements are particularly notable in the development of biocompatible and flexible sensors, as well as e-skin multifunctional circuits. Despite these advancements, the practical application of OECTs, where n-type and p-type materials complement each other, is challenging. This is largely due to the performance disparity between p-type and n-type organic mixed ionic-electronic conductors (OMIECs) used in OECT channels, with n-type OMIECs facing issues, such as low electron mobility, slow operation speed, and instability. To address these challenges, this study focuses on exploring the operational characteristics of n-type OECTs using newly synthesized X-material. The research demonstrates that OECTs utilizing X-material exhibit impressive performance metrics, including high charge carrier mobility, rapid transient response, and enhanced long-term stability. All results indicate that X-material can effectively complement p-type counterparts. Furthermore, the study introduces an innovative concept in the form of an anti-ambipolar electrochemical transistor. This transistor operates through ion injection-driven resistance modulation, presenting a novel approach to transistor design. Overall, this research significantly contributes to enhancing the performance of next-generation organic electronic devices, potentially revolutionizing the field. | - |
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