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Surfactant-free co-solvent exfoliation strategy for semiconducting quasi-1D Nb2Pd3Se8 nanowiresoa mark
  • Choi, Kyung Hwan ;
  • Kim, Yeongjin ;
  • Kang, Jinsu ;
  • Kim, Kyung In ;
  • Park, Jeong Su ;
  • Oh, Hyung Suk ;
  • Yu, Hak Ki ;
  • Choi, Jae Young
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Publication Year
2025-01-21
Journal
CrystEngComm
Publisher
Royal Society of Chemistry
Citation
CrystEngComm, Vol.27 No.9, pp.1292-1296
Mesh Keyword
CosolventsDispersion behaviorIsopropanolOptimal solventsOptoelectrical propertiesQuasi-one dimensionalQuasi-one-dimensionalSolvent exfoliationsSurfactant-freeVan der Waal
All Science Classification Codes (ASJC)
Chemistry (all)Materials Science (all)Condensed Matter Physics
Abstract
Nb2Pd3Se8, a quasi-one-dimensional (1D) van der Waals material, has recently gained attention owing to its intriguing structural, electrical and optoelectrical properties. In this work, we studied co-solvent exfoliation of Nb2Pd3Se8 in a mixture of water and ethanol or isopropanol. By adjusting the compositions of the co-solvent, the dispersion behavior of Nb2Pd3Se8 was interpreted in terms of surface tension and dielectric constant. This approach is effective for substituting the previously reported optimal solvent of NMP, which is toxic with a high boiling point of 204 °C. The Nb2Pd3Se8 nanowire prepared through co-solvent exfoliation presented a high electronic property with an electron mobility of 10.3 cm2 V−1 s−1
ISSN
1466-8033
Language
eng
URI
https://aurora.ajou.ac.kr/handle/2018.oak/38472
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85216880571&origin=inward
DOI
https://doi.org/10.1039/d4ce01136h
Journal URL
http://pubs.rsc.org/en/journals/journal/ce
Type
Article
Funding
This research was supported by the National Research Foundation (NRF) grant funded by the Korea government (MSIT) (No. RS-2023-00208311). In addition, this work was supported by the KIST Institutional Program (Project No. 2E31854-22-066) from the Korea Institute of Science and Technology.
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Yu, Hak Ki류학기
Department of Materials Science Engineering
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