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Synthesis and structure of new two-dimensional group 4 metal palladium sulfides, A2MPd3S6 (A = Rb, M = Hf; A = Cs, M = Zr, Hf)
  • Yoon, Woojin ;
  • Park, Hyeongyu ;
  • Bae, Sanghyun ;
  • Dong, Yongkwan ;
  • Yun, Hoseop
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dc.contributor.authorYoon, Woojin-
dc.contributor.authorPark, Hyeongyu-
dc.contributor.authorBae, Sanghyun-
dc.contributor.authorDong, Yongkwan-
dc.contributor.authorYun, Hoseop-
dc.date.issued2022-04-01-
dc.identifier.issn1229-5949-
dc.identifier.urihttps://aurora.ajou.ac.kr/handle/2018.oak/32509-
dc.identifier.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85123914913&origin=inward-
dc.description.abstractA series of new quaternary group 4 metal palladium sulfides, A2MPd3S6 (A = Rb, M = Hf; A = Cs, M = Zr, Hf) have been prepared from elements with the use of alkali metal halide fluxes and they are structurally characterized by single crystal x-ray diffraction methods. They are isostructural and the structure of the title compounds consists of anionic (Formula presented.) [MPd3S62−] slabs and alkali metal ions. In the slab, the group 4 metals are surrounded by six S atoms in a trigonal prismatic fashion and the Pd atoms are coordinated with four S atoms in square planar fashion. Two hexagons made of six edge-sharing square planar PdS4 are interconnected by two trigonal prismatic MS6 to form the basic repeating unit, M2Pd12S28. These are linked together to form the infinite two-dimensional (Formula presented.) [MPd3S62−] slabs. These slabs stack on top of each other and they are separated by alkali metal cations. There is no strong S-S bonding interaction in this phase and the charge valence of the title compounds could be expressed as [A+]2[M4+][Pd2+]3[S2−]6 (A = Rb, M = Hf; A = Cs, M = Zr, Hf).-
dc.description.sponsorshipMinistry of Education, Grant/Award Number: 2019R1I1A2A01058066; National Research Foundation of Korea (NRF); Korean Institute of Energy Technology Evaluation and Planning (KETEP), Grant/Award Number: 20184030202220 Funding information-
dc.description.sponsorshipThis work was supported by “Human Resources Program in Energy Technology” of the Korean Institute of Energy Technology Evaluation and Planning (KETEP), granted financial resource from the Ministry of Trade, Industry & Energy, Republic Korea. (Project No: 20184030202220). x‐Ray structural analysis was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2019R1I1A2A01058066).-
dc.language.isoeng-
dc.publisherJohn Wiley and Sons Inc-
dc.subject.meshAlkali metal halides-
dc.subject.meshAlkali-metal ions-
dc.subject.meshEdge sharing-
dc.subject.meshGroup 4-
dc.subject.meshIsostructural-
dc.subject.meshPd atoms-
dc.subject.meshRepeating unit-
dc.subject.meshSingle crystal X-ray diffraction method-
dc.subject.meshTitle compounds-
dc.subject.meshTwo-dimensional-
dc.titleSynthesis and structure of new two-dimensional group 4 metal palladium sulfides, A2MPd3S6 (A = Rb, M = Hf; A = Cs, M = Zr, Hf)-
dc.typeArticle-
dc.citation.endPage601-
dc.citation.number4-
dc.citation.startPage595-
dc.citation.titleBulletin of the Korean Chemical Society-
dc.citation.volume43-
dc.identifier.bibliographicCitationBulletin of the Korean Chemical Society, Vol.43 No.4, pp.595-601-
dc.identifier.doi10.1002/bkcs.12501-
dc.identifier.scopusid2-s2.0-85123914913-
dc.identifier.urlhttp://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1229-5949-
dc.subject.keywordcrystal structure-
dc.subject.keywordtransition metal palladium sulfide-
dc.subject.keywordtwo-dimensional layer-
dc.type.otherArticle-
dc.identifier.pissn0253-2964-
dc.description.isoafalse-
dc.subject.subareaChemistry (all)-
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