Citation Export
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Son, Soobin | - |
| dc.contributor.author | Shyam, Pranab K. | - |
| dc.contributor.author | Park, Hyowon | - |
| dc.contributor.author | Jeong, Ilgyo | - |
| dc.contributor.author | Jang, Hye Young | - |
| dc.date.issued | 2018-07-06 | - |
| dc.identifier.issn | 1099-0690 | - |
| dc.identifier.uri | https://aurora.ajou.ac.kr/handle/2018.oak/30281 | - |
| dc.identifier.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85049567438&origin=inward | - |
| dc.description.abstract | The regioselective synthesis of variously substituted β-hydroxysulfones from thiosulfonates was developed. The reactions of thiosulfonates and alkenes via a peroxy radical intermediate provided 2° and 3° β-hydroxysulfones in good yields. The presence of epoxides instead of alkenes changed the reaction mechanism to nucleophilic addition involving sulfinate anions to afford 1° and 2° β-hydroxysulfones. By using both protocols, the regiochemical outcome of the β-hydroxysulfones synthesized from thiosulfonates was diversified. | - |
| dc.description.sponsorship | This study was supported by the C1 refinery program (2015M3D3A1A01065436), the National Research Foundation of Korea (No. 2016R1D1A1A09917100), and the Ministry of Trade, Industry & Energy, Republic of Korea through the Human Resources Program in Energy Technology (No. 20154010200820) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP). | - |
| dc.language.iso | eng | - |
| dc.publisher | Wiley-VCH Verlag | - |
| dc.title | Complementary Strategy for Regioselective Synthesis of Diverse β-Hydroxysulfones from Thiosulfonates | - |
| dc.type | Article | - |
| dc.citation.endPage | 3371 | - |
| dc.citation.number | 25 | - |
| dc.citation.startPage | 3365 | - |
| dc.citation.title | European Journal of Organic Chemistry | - |
| dc.citation.volume | 2018 | - |
| dc.identifier.bibliographicCitation | European Journal of Organic Chemistry, Vol.2018 No.25, pp.3365-3371 | - |
| dc.identifier.doi | 10.1002/ejoc.201800778 | - |
| dc.identifier.scopusid | 2-s2.0-85049567438 | - |
| dc.identifier.url | http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1099-0690 | - |
| dc.subject.keyword | Radical reactions | - |
| dc.subject.keyword | Reaction mechanisms | - |
| dc.subject.keyword | Sulfones | - |
| dc.subject.keyword | Sulfonylation | - |
| dc.subject.keyword | Synthesis design | - |
| dc.type.other | Article | - |
| dc.identifier.pissn | 1434-193X | - |
| dc.description.isoa | false | - |
| dc.subject.subarea | Physical and Theoretical Chemistry | - |
| dc.subject.subarea | Organic Chemistry | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
