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DC Field | Value | Language |
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dc.contributor.advisor | 이동주 | - |
dc.contributor.author | 손유희 | - |
dc.date.issued | 2022-02 | - |
dc.identifier.other | 31760 | - |
dc.identifier.uri | https://aurora.ajou.ac.kr/handle/2018.oak/21182 | - |
dc.description | 학위논문(석사)--아주대학교 일반대학원 :약학과,2022. 2 | - |
dc.description.tableofcontents | I. Introduction 1 II. Results and Discussion 3 III. Conclusion 9 IV. Experimental Section 10 1. Materials and Methods 10 2. Full Experimental Procedures and Analytical Data of Compounds 11 V. References 28 VI. Appendix 31 | - |
dc.language.iso | eng | - |
dc.publisher | The Graduate School, Ajou University | - |
dc.rights | 아주대학교 논문은 저작권에 의해 보호받습니다. | - |
dc.title | Stereoselective Total Syntheses of Tsaokopyranols (–)-E, (–)-L, (+)-M, (+)- Jughopnin J, and (–)-Engelheptanoxide A | - |
dc.type | Thesis | - |
dc.contributor.affiliation | 아주대학교 일반대학원 | - |
dc.contributor.alternativeName | Yuhui Son | - |
dc.contributor.department | 일반대학원 약학과 | - |
dc.date.awarded | 2022. 2 | - |
dc.description.degree | Master | - |
dc.identifier.uci | I804:41038-000000031760 | - |
dc.identifier.url | https://dcoll.ajou.ac.kr/dcollection/common/orgView/000000031760 | - |
dc.subject.keyword | (+)-Jughopnin J | - |
dc.subject.keyword | (+)-Tsaokopyranol M | - |
dc.subject.keyword | (–)-Engelheptanoxide A | - |
dc.subject.keyword | (–)-Tsaokopyranol E | - |
dc.subject.keyword | (–)-Tsaokopyranol L | - |
dc.subject.keyword | Dehydrogenative cycloetherification | - |
dc.subject.keyword | Diastereoselectivity | - |
dc.subject.keyword | Natural Products | - |
dc.subject.keyword | trans-2-Alkyl-6-aryl-3 | - |
dc.subject.keyword | 6-dihydro2H-pyran | - |
dc.description.alternativeAbstract | The stereoselective total syntheses of naturally occurring bioactive 2,6-epoxydiarylheptanoids tsaokopyranols (–)-E, (–)-L, (+)-M, (+)-jughopnin J, and (–)-engelheptanoxide A have been accomplished in 4–6 steps starting from a chiral epoxide utilizing dehydrogenative cycloetherification and epimerization of trans- to cis-2-alkyl-6-aryl-3,6-dihydro-2H-pyran framework as the key steps. The absolute configuration of natural tsaokopyranol L was revised. | - |
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