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Study on Quantum Efficiency Improvement of Te-free Blue Emitting Zinc Selenide Quantum Dots
  • 하진수
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dc.contributor.advisor김상욱-
dc.contributor.author하진수-
dc.date.issued2022-08-
dc.identifier.other31997-
dc.identifier.urihttps://aurora.ajou.ac.kr/handle/2018.oak/21000-
dc.description학위논문(석사)--아주대학교 일반대학원 :분자과학기술학과,2022. 8-
dc.description.tableofcontentsIntroduction 1 Experimental Section 3 Results and Discussion 5 Conclusion 9 References 16-
dc.language.isoeng-
dc.publisherThe Graduate School, Ajou University-
dc.rights아주대학교 논문은 저작권에 의해 보호받습니다.-
dc.titleStudy on Quantum Efficiency Improvement of Te-free Blue Emitting Zinc Selenide Quantum Dots-
dc.typeThesis-
dc.contributor.affiliation아주대학교 일반대학원-
dc.contributor.department일반대학원 분자과학기술학과-
dc.date.awarded2022. 8-
dc.description.degreeMaster-
dc.identifier.uciI804:41038-000000031997-
dc.identifier.urlhttps://dcoll.ajou.ac.kr/dcollection/common/orgView/000000031997-
dc.subject.keywordQuantum Dots-
dc.subject.keywordTe-free Blue-
dc.subject.keywordZinc Selenide-
dc.description.alternativeAbstractRecently, due to the miniaturization of display backlights, interest in blue light-emitting quantum dots is increasing. Quantum dots are attracting attention as a next-generation display material with high color gamut, but the development of blue QDs is necessary to realize perfect self-luminous QLEDs. The inherent inferior photophysical properties of blue light-emitting materials remain a challenge. Many groups have implemented Cd-based quantum dots, but it is unknown whether they can be used commercially due to the toxicity of Cds. Therefore, it is necessary to develop a Cd-free and eco-friendly blue QD. Here, we present the synthesis of ZnSe-based blue-emitting quantum dots using a fast-reactive bis(trimethylsilyl)selenium compound. Light emission of 440 nm to 460 nm or more was obtained by using the SILAR method, which is a method in which positive and negative ions are alternately added. We also performed spectral analysis according to the ratio of Zn to Se. In addition, high-efficiency blue QDs and a maximum quantum yield of 53.2% were achieved by using a hydrofluoric acid and zinc chloride additive to remove stacking defects in the ZnSe crystal structure to increase the luminous efficiency.-
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