Recently, there has been extensive research on modulating band structures using MnCr2O4, which has gained significant attention as a photocatalyst. However, due to thermodynamic constraints, conventional modulation of band structures using two compositions poses challenges. Therefore, we utilized a high-entropy approach to easily modulate band structures by forming multi-composition systems (three-composition oxides or higher). The spinel structure of Mn0.68Cr0.8Rh0.64Co0.87O4 produced via electrospinning enabled the fabrication of nano fibers with an average diameter of 160 nm at a calcination temperature of 900 °C, and these nano fibers were crystallized through various analytical instruments. Furthermore, nanofibers calcined at 900 °C exhibited high responsivity and fast rise, decay times under a light source with a wavelength of 635 nm. Thus, with such high reactivity, fast response time, and clear selectivity, Mn0.68Cr0.8Rh0.64Co0.87O4 indicates promising potential as a material for future photo-catalytic research.
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. RS-2023\u201300208311, RS-2023\u201300252880, and NRF-2018R1A6A1A03025340)This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. RS-2023-00208311, RS-2023-00252880, and NRF-2018R1A6A1A03025340)
