The dry reforming of methane (DRM) is a promising method for controlling greenhouse gas emissions by converting CO2 and CH4 into syngas, a mixture of CO and H2. Ni-based catalysts have been intensively investigated for their use in the DRM. However, they are limited by the formation of carbonaceous materials on their surfaces. In this review, we explore carbon-induced catalyst deactivation mechanisms and summarize the recent research progress in controlling and mitigating carbon deposition by developing coke-resistant Ni-based catalysts. This review emphasizes the significance of support, alloy, and catalyst structural strategies, and the importance of comprehending the interactions between catalyst components to achieve improved catalytic performance and stability.
This work was supported by the C1 Gas Refinery Program of the National Research Foundation (NRF) of Korea and funded by the Ministry of Science, ICT, and Future Planning (2015M3D3A1A01064899). This research was also supported by the H2KOREA funded by the Ministry of Education (2002Hydrogen fuel cell-002, Innovative Human Resource Development Project for Hydrogen Fuel Cells).
