High-entropy alloys have exceptional oxidation resistance due to their passive oxide film. In this study, photoelectron spectroscopy was used in a modern atomic-scale in situ initial oxidation analysis process to determine the oxidation behavior and elemental variation on its breakdown. Furthermore, the behavior of natural oxide formed on the AlFeCuCrMg1.5 HEA after the exposure of the alloy to the atmosphere for one hour, one day, and seven days was investigated in detail. Through a survey scan, the elements present on the oxidized surface were determined and quantified. Additionally, the seven-day-exposed HEA was depth-profiled and discovered drastic modifications in the alloy.
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government ( MSIT ) ( 2021R1A2C1005478 ). This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2022R1I1A1A01053047 and 2021R1A6A1A10044950). This work was supported by the Ajou University research fund.
