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Ir(tri-N-heterocyclic carbene)-catalyzed upgrading of glycerol: C-C bond formation for the synthesis of α-hydroxy acidsoa mark
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dc.contributor.authorByeon, Heemin-
dc.contributor.authorKim, Jaeho-
dc.contributor.authorLee, Mi Hyun-
dc.contributor.authorJang, Hye Young-
dc.date.issued2024-01-30-
dc.identifier.issn1477-0520-
dc.identifier.urihttps://dspace.ajou.ac.kr/dev/handle/2018.oak/33934-
dc.description.abstractIr(triNHC) complexes catalyzed glycerol and alcohol dehydrogenative coupling, yielding diverse α-hydroxy acids. Unlike conventional conditions, Ir(triNHC) facilitated additional C-C bond formation after lactic acid production from glycerol, exhibiting high TOFs. This protocol successfully converted 1,2-propanediol and sorbitol into α-hydroxy acids, highlighting biomass-derived sources’ potential as valuable platform chemicals.-
dc.description.sponsorshipThis study was supported by the Carbon to X Program (No. 2020M3H7A1098283) and National Research Foundation Program (No. 2022R1A2C1004387) by the Ministry of Science and ICT, and the H2KOREA funded by the Ministry of Education (2022Hydrogen fuel cell-002), Innovative Human Resources Development Project for Hydrogen Fuel Cells.-
dc.language.isoeng-
dc.publisherRoyal Society of Chemistry-
dc.subject.meshC-C bond formation-
dc.subject.meshCondition-
dc.subject.meshDehydrogenative coupling-
dc.subject.meshHydroxy acids-
dc.subject.meshLactic acid production-
dc.subject.meshN-heterocyclic carbenes-
dc.subject.meshPlatform chemicals-
dc.subject.meshPropanediols-
dc.subject.meshSource potentials-
dc.titleIr(tri-N-heterocyclic carbene)-catalyzed upgrading of glycerol: C-C bond formation for the synthesis of α-hydroxy acids-
dc.typeArticle-
dc.citation.endPage1618-
dc.citation.startPage1613-
dc.citation.titleOrganic and Biomolecular Chemistry-
dc.citation.volume22-
dc.identifier.bibliographicCitationOrganic and Biomolecular Chemistry, Vol.22, pp.1613-1618-
dc.identifier.doi10.1039/d3ob02035e-
dc.identifier.pmid38305776-
dc.identifier.scopusid2-s2.0-85183999417-
dc.identifier.urlhttp://pubs.rsc.org/en/journals/journal/ob-
dc.description.isoatrue-
dc.subject.subareaBiochemistry-
dc.subject.subareaPhysical and Theoretical Chemistry-
dc.subject.subareaOrganic Chemistry-
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