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Sulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactoroa mark
  • Jo, Yong Su ;
  • Abdullaev, Mansurbek ;
  • Jin, Gwang Hwa ;
  • Swain, Bhabani Sankar ;
  • Lee, Byongpil ;
  • Eom, Hyung Sub ;
  • Min, Seok Hong ;
  • Kim, Seok Ki ;
  • Kim, Young Keun ;
  • Yang, Seung Min
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dc.contributor.authorJo, Yong Su-
dc.contributor.authorAbdullaev, Mansurbek-
dc.contributor.authorJin, Gwang Hwa-
dc.contributor.authorSwain, Bhabani Sankar-
dc.contributor.authorLee, Byongpil-
dc.contributor.authorEom, Hyung Sub-
dc.contributor.authorMin, Seok Hong-
dc.contributor.authorKim, Seok Ki-
dc.contributor.authorKim, Young Keun-
dc.contributor.authorYang, Seung Min-
dc.date.issued2022-12-06-
dc.identifier.issn2470-1343-
dc.identifier.urihttps://dspace.ajou.ac.kr/dev/handle/2018.oak/33085-
dc.description.abstractIn this study, we investigated the effect of the sulfur content in the NiCl2 precursor on the shape of nickel nanoparticles (Ni-NPs) prepared by chemical vapor synthesis. We obtained spherical Ni-NPs when using anhydrous NiCl2 mixed with NiSO4 or Na2SO4 with a molar ratio of 0.002 as precursors without changing any other process parameters whereas faceted Ni-NPs when using only anhydrous NiCl2 as a precursor. First-principles calculations supported experimental results, which showed that NiSO4-mixed NiCl2 and Na2SO4-mixed NiCl2 precursors favored the growth of spherical NPs.-
dc.description.sponsorshipThis study was supported by the Korea Institute of Industrial Technology [grant number UR220003] and the National Research Foundation of Korea [grant number 2021M3H4A6A03103721 and 2202R1F1A1075082].-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.titleSulfur-Mediated Synthesis of Spherical Nickel Nanoparticles in a Chemical Vapor Reactor-
dc.typeArticle-
dc.citation.endPage43964-
dc.citation.startPage43958-
dc.citation.titleACS Omega-
dc.citation.volume7-
dc.identifier.bibliographicCitationACS Omega, Vol.7, pp.43958-43964-
dc.identifier.doi10.1021/acsomega.2c05281-
dc.identifier.scopusid2-s2.0-85143078702-
dc.identifier.urlpubs.acs.org/journal/acsodf-
dc.description.isoatrue-
dc.subject.subareaChemistry (all)-
dc.subject.subareaChemical Engineering (all)-
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