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(Iminopyridine)Pd (II) complexes as versatile catalysts for copolymerization and terpolymerization of vinyl arene, ethylene, and carbon monoxide
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dc.contributor.authorLee, Seulchan-
dc.contributor.authorChae, Ju Hyung-
dc.contributor.authorYang, Yongmoon-
dc.contributor.authorLee, In Hwan-
dc.contributor.authorJang, Hye Young-
dc.date.issued2021-09-01-
dc.identifier.urihttps://dspace.ajou.ac.kr/dev/handle/2018.oak/32090-
dc.description.abstractPalladium catalysts modified with iminopyridine ligands were employed for ethylene/CO and styrene/CO copolymerization and ethylene/styrene/CO terpolymerization. Our studies revealed that the steric and electronic effects of the catalysts play key, yet distinct roles in these polymerization reactions. The thermal properties of the polyketones were engineered by varying the styrene content in terpolymers derived from ethylene, styrene, and CO sources, with increased styrene ratios yielding reduced polyketone crystallinity.-
dc.description.sponsorshipThis study was supported by the National Research Foundation of Korea (Nos. 2015M3D3A1A01065436, 2019R1A2C1084021, and 2020M3H7A1098281).-
dc.language.isoeng-
dc.publisherJohn Wiley and Sons Ltd-
dc.subject.meshElectronic effects-
dc.subject.meshPalladium catalyst-
dc.subject.meshPd complex-
dc.subject.meshPolyketones-
dc.subject.meshPolymerization reaction-
dc.title(Iminopyridine)Pd (II) complexes as versatile catalysts for copolymerization and terpolymerization of vinyl arene, ethylene, and carbon monoxide-
dc.typeArticle-
dc.citation.titleApplied Organometallic Chemistry-
dc.citation.volume35-
dc.identifier.bibliographicCitationApplied Organometallic Chemistry, Vol.35-
dc.identifier.doi10.1002/aoc.6337-
dc.identifier.scopusid2-s2.0-85108083975-
dc.identifier.urlhttp://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1099-0739-
dc.subject.keywordcarbon monoxide-
dc.subject.keywordolefin-
dc.subject.keywordpalladium complex-
dc.subject.keywordpolyketone-
dc.subject.keywordpolymerization-
dc.description.isoafalse-
dc.subject.subareaChemistry (all)-
dc.subject.subareaInorganic Chemistry-
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