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Valorization of Click-Based Microporous Organic Polymer: Generation of Mesoionic Carbene-Rh Species for the Stereoselective Synthesis of Poly(arylacetylene)s
  • Cho, Kyoungil ;
  • Yang, Hee Seong ;
  • Lee, In Hwan ;
  • Lee, Sang Moon ;
  • Kim, Hae Jin ;
  • Son, Seung Uk
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dc.contributor.authorCho, Kyoungil-
dc.contributor.authorYang, Hee Seong-
dc.contributor.authorLee, In Hwan-
dc.contributor.authorLee, Sang Moon-
dc.contributor.authorKim, Hae Jin-
dc.contributor.authorSon, Seung Uk-
dc.date.issued2021-03-24-
dc.identifier.urihttps://dspace.ajou.ac.kr/dev/handle/2018.oak/31944-
dc.description.abstractThis work reports the functionalization of azide-Alkyne click-based microporous organic polymer (CMOP). The generation of triazolium salts and successive deprotonation induced mesoionic carbene species in hollow CMOP (H-CMOP). Rh(I) species could be coordinated to the mesoionic carbene species to form H-CMOP-Rh, showing excellent heterogeneous catalytic performance in the stereoselective polymerization of arylacetylenes.-
dc.description.sponsorshipThis work was supported by \u201cCarbon to X Project\u201d (No. 2020M3H7A1098283) and Grant 2020R1A2C2004310 through the National Research Foundation (NRF) funded by the Ministry of Science and ICT, Republic of Korea.-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.subject.meshArylacetylenes-
dc.subject.meshCatalytic performance-
dc.subject.meshFunctionalizations-
dc.subject.meshMesoionic carbene-
dc.subject.meshMicroporous organic polymers-
dc.subject.meshStereoselective polymerization-
dc.subject.meshStereoselective synthesis-
dc.titleValorization of Click-Based Microporous Organic Polymer: Generation of Mesoionic Carbene-Rh Species for the Stereoselective Synthesis of Poly(arylacetylene)s-
dc.typeArticle-
dc.citation.endPage4105-
dc.citation.startPage4100-
dc.citation.titleJournal of the American Chemical Society-
dc.citation.volume143-
dc.identifier.bibliographicCitationJournal of the American Chemical Society, Vol.143, pp.4100-4105-
dc.identifier.doi10.1021/jacs.0c13286-
dc.identifier.pmid33687196-
dc.identifier.scopusid2-s2.0-85103469348-
dc.identifier.urlhttp://pubs.acs.org/journal/jacsat-
dc.description.isoafalse-
dc.subject.subareaCatalysis-
dc.subject.subareaChemistry (all)-
dc.subject.subareaBiochemistry-
dc.subject.subareaColloid and Surface Chemistry-
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Lee, In-Hwan 이인환
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