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Mononuclear Copper Complexes with Tridentate Tris(N-heterocyclic carbene): Synthesis and Catalysis of Alkyne-Azide Cycloaddition
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dc.contributor.authorSeo, Changhyeon-
dc.contributor.authorCheong, Yeon Joo-
dc.contributor.authorYoon, Woojin-
dc.contributor.authorKim, Jaegyeom-
dc.contributor.authorShin, Jinho-
dc.contributor.authorYun, Hoseop-
dc.contributor.authorKim, Seung Joo-
dc.contributor.authorJang, Hye Young-
dc.date.issued2021-01-11-
dc.identifier.urihttps://dspace.ajou.ac.kr/dev/handle/2018.oak/31761-
dc.description.abstractMononuclear copper complexes modified with tridentate tris(N-heterocyclic carbene) (triscarbene) ligands are synthesized. The structures of the copper-triscarbene complexes are characterized using X-ray crystallography, X-ray absorption near edge structure (XANES), and extended X-ray absorption fine structure (EXAFS) analyses. These copper-triscarbene complexes are utilized for the cycloaddition of alkynes and azides, and kinetic study results are presented.-
dc.description.sponsorshipThis study was supported by the National Research Foundation program (No. 2019R1A2C1084021) and the Carbon to X Program (No. 2020M3H7A1098283) of Ministry of Science and ICT, Republic of Korea. X-ray structural analysis was supported by Basic Science Research Program through the National Research Foundation of Korea funded by the Ministry of Education (2019R1I1A2A01058066).-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.subject.meshExtended x-ray absorption fine structure analysis-
dc.subject.meshKinetic study-
dc.subject.meshMononuclear copper complexes-
dc.subject.meshN-heterocyclic carbenes-
dc.subject.meshX-ray absorption near-edge structure-
dc.titleMononuclear Copper Complexes with Tridentate Tris(N-heterocyclic carbene): Synthesis and Catalysis of Alkyne-Azide Cycloaddition-
dc.typeArticle-
dc.citation.endPage22-
dc.citation.startPage16-
dc.citation.titleOrganometallics-
dc.citation.volume40-
dc.identifier.bibliographicCitationOrganometallics, Vol.40, pp.16-22-
dc.identifier.doi10.1021/acs.organomet.0c00457-
dc.identifier.scopusid2-s2.0-85099095076-
dc.identifier.urlhttp://pubs.acs.org/loi/orgnd7-
dc.description.isoafalse-
dc.subject.subareaPhysical and Theoretical Chemistry-
dc.subject.subareaOrganic Chemistry-
dc.subject.subareaInorganic Chemistry-
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Kim, Seung-Joo김승주
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