Oxygen molecules breakdown to atoms by impact dissociation of electrons in a microwave oxygen torch. Typical atom density of oxygen in a microwave torch is a few times of 1018/cm3 produced within millisecond time scale. Dwelling time of an oxygen fluid element in a discharge tube is longer than 10 milliseconds, which is much longer than the atom production time. The oxidation coefficient of hydrocarbon fuel in oxygen atoms is usually about one million times faster than that in oxygen molecules. As an example of applications, oxygen atoms are applied to dimethyl ether, which is relatively a large molecular structure. The initial breakdown species of DME molecules in a high-temperature reaction chamber are hydrogen, carbon monoxide and methane, which is also breakdown to CO and H2 by oxygen atoms. Abundance of water may be generated in a reaction chamber of relatively low-temperature lower than Tg = 1500K, hindering an efficient production of synthetic gas. DME disintegration in a hot chamber by a microwave oxygen torch is experimentally observed. Experimental observation is somewhat agreeing with theoretical predictions.
This work was supported by the 2017 Open R&D Program of the Korea Electric Power Corporation (KEPCO) under Grant R17EH02. The authors particularly appreciate Mr. In Chul Chung for helping with the gasifier fabrication. Dr. Yong C. Hong helped with the use of the gas analyzer.This work was supported by the 2017 Open R&D Program of the Korea Electric Power Corporation (KEPCO) under Grant R17EH02. The authors particularly appreciate Mr. In Chul Chung for helping with the gasifier fabrication. Dr. Yong C. Hong helped with the use of the gas analyzer.
