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Large-scale synthesis of van der Waals 1-dimensional material Mo6S3I6 by using a MoI2 precursor
  • Oh, Seungbae ;
  • Chae, Sudong ;
  • Choi, Kyung Hwan ;
  • Kim, Bum Jun ;
  • Lee, Sang Hoon ;
  • Wang, Cong ;
  • Liu, Zhixiang ;
  • Jeon, Jiho ;
  • Lee, Jae Hyun ;
  • Yu, Hak Ki ;
  • Choi, Jae Young
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dc.contributor.authorOh, Seungbae-
dc.contributor.authorChae, Sudong-
dc.contributor.authorChoi, Kyung Hwan-
dc.contributor.authorKim, Bum Jun-
dc.contributor.authorLee, Sang Hoon-
dc.contributor.authorWang, Cong-
dc.contributor.authorLiu, Zhixiang-
dc.contributor.authorJeon, Jiho-
dc.contributor.authorLee, Jae Hyun-
dc.contributor.authorYu, Hak Ki-
dc.contributor.authorChoi, Jae Young-
dc.date.issued2019-09-30-
dc.identifier.issn0925-8388-
dc.identifier.urihttps://dspace.ajou.ac.kr/dev/handle/2018.oak/30790-
dc.description.abstractBy using a MoI2 precursor, a one-dimensional linear chain material, Mo6S3I6, was synthesized on a centimeter scale. As MoI2 can be used to form Mo6S3I6 through a gas-phase reaction, a larger amount of single crystals can be synthesized; moreover, these crystals are significantly longer than those synthesized by using Mo, S, and I powder. The synthesized Mo6S3I6 exhibited the characteristics of paramagnetic semiconductors with excellent thermal stability and a low bandgap. Furthermore, Mo6S3I6 can be separated into long nanometer-scale chains by a solution dispersion process.-
dc.description.sponsorshipFunding: This work was supported by the Nano Material Technology Development Program through the National Research Foundation of Korea (NRF) , as funded by the Ministry of Science and ICT [grant numbers 2017M3A7B8065561 , NRF-2019R1A2C1006972 ]; and a National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) [grant number NRF-2017R1A4A1015770 ].-
dc.description.sponsorshipFunding: This work was supported by the Nano Material Technology Development Program through the National Research Foundation of Korea (NRF), as funded by the Ministry of Science and ICT [grant numbers 2017M3A7B8065561, NRF-2019R1A2C1006972]; and a National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) [grant number NRF-2017R1A4A1015770].-
dc.language.isoeng-
dc.publisherElsevier Ltd-
dc.subject.mesh1D materials-
dc.subject.meshCentimeter-scale-
dc.subject.meshDispersion process-
dc.subject.meshGas-phase reactions-
dc.subject.meshLarge scale synthesis-
dc.subject.meshMo6S3I6-
dc.subject.meshMoI2 precursor-
dc.subject.meshNano-meter scale-
dc.titleLarge-scale synthesis of van der Waals 1-dimensional material Mo6S3I6 by using a MoI2 precursor-
dc.typeArticle-
dc.citation.endPage504-
dc.citation.startPage499-
dc.citation.titleJournal of Alloys and Compounds-
dc.citation.volume803-
dc.identifier.bibliographicCitationJournal of Alloys and Compounds, Vol.803, pp.499-504-
dc.identifier.doi10.1016/j.jallcom.2019.06.287-
dc.identifier.scopusid2-s2.0-85068066741-
dc.identifier.urlhttps://www.journals.elsevier.com/journal-of-alloys-and-compounds-
dc.subject.keyword1D materials-
dc.subject.keywordCentimeter-scale synthesis-
dc.subject.keywordMo6S3I6-
dc.subject.keywordMoI2 precursor-
dc.description.isoafalse-
dc.subject.subareaMechanics of Materials-
dc.subject.subareaMechanical Engineering-
dc.subject.subareaMetals and Alloys-
dc.subject.subareaMaterials Chemistry-
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