Citation Export
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kim, Hyoungsu | - |
| dc.contributor.author | Choi, Hosam | - |
| dc.contributor.author | Lee, Kiyoun | - |
| dc.date.issued | 2018-06-01 | - |
| dc.identifier.uri | https://dspace.ajou.ac.kr/dev/handle/2018.oak/30105 | - |
| dc.description.abstract | A concise total synthesis of (±)-mesembrine has been successfully accomplished in seven steps and 24% overall yield from commercially available 3-ethoxy-2-cyclohexen-1-one. Central to the assembly of the skeleton of mesembrine are a Johnson-Claisen rearrangement for the formation of the benzylic quaternary stereocenter and direct allylic oxidation to generate the substrate for the amidation/transannular aza-conjugate addition reaction. | - |
| dc.description.sponsorship | This work was supported by the Basic Science Research Program from the National Research Foundation of Korea (NRF-2016R1C1B1008816) funded by the Ministry of Education and the 2017 Research Fund of the Catholic University of Korea.Noaitnal Reseacrh Foundoaitn of Koera N(RF-2016R1C1B1008816) | - |
| dc.language.iso | eng | - |
| dc.publisher | Georg Thieme Verlag | - |
| dc.title | A Concise Total Synthesis of (±)-Mesembrine | - |
| dc.type | Article | - |
| dc.citation.endPage | 1206 | - |
| dc.citation.startPage | 1203 | - |
| dc.citation.title | Synlett | - |
| dc.citation.volume | 29 | - |
| dc.identifier.bibliographicCitation | Synlett, Vol.29, pp.1203-1206 | - |
| dc.identifier.doi | 10.1055/s-0036-1591547 | - |
| dc.identifier.scopusid | 2-s2.0-85042192991 | - |
| dc.identifier.url | http://www.thieme-connect.com/ejournals/toc/synlett | - |
| dc.subject.keyword | 3a-(aryl)octahydro-indole | - |
| dc.subject.keyword | allylic transfer | - |
| dc.subject.keyword | benzylic quaternary stereogenic center | - |
| dc.subject.keyword | mesembrine | - |
| dc.subject.keyword | natural products | - |
| dc.subject.keyword | total synthesis | - |
| dc.description.isoa | false | - |
| dc.subject.subarea | Organic Chemistry | - |
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